(A) Overlaid NMR spectra that defines DPFGE (top) and OIV-MA-AS316-01 (bottom) metabolomics outliers; (B): Stacked NMR spectra that defines DPFGE (top) and OIV-MA-AS316-01 (bottom) metabolomics outliers and (C): OPLS-DA loading p[1] S-plots of DPFGE (top) and OIV-MA-AS316-01 (bottom) data matrixes, as a function of ¹H –NMR chemical shifts, indicating the importance of relevant metabolites to respectively discriminate fermentation schemes of wines from same variety -geographical origin and geographical origins of wines from diverse grape varieties and year of vintages.