BIO Web Conf.
Volume 8, 20172016 International Conference on Medicine Sciences and Bioengineering (ICMSB2016)
|Number of page(s)||8|
|Section||Session III: Biomedical Engineering|
|Published online||11 January 2017|
Synthesis and Characterization of Magnetic-Graphene Molecularly Imprinted Polymers for Selective Recognition of Ltryptophan
1 Guangdong Provincial Key Laboratory of Food Quality and Safety, College of Food Science, South China Agricultural University
2 New Rural Development Institute of South China Agricultural University
a Corresponding author: firstname.lastname@example.org
In this paper, a novel molecular imprinted polymer using L-tryptophan(L-Trp) as the template, dopamine(DA) as both functional monomer and cross linking agent, magnetic graphene as the supporting matrix was synthesized. The prepared magnetic-graphene molecularly imprinted polymers(Fe3O4@GO-MIPs) were characterized by Fourier transform infrared spectrometer(FT-IR), transmission electron microscopy (TEM), vibrating sample magnetometer (VSM), respectively. The results showed that when the molar ratio of L- tryptophan and dopamine was 1:4 and the reaction temperature was 60 °C, Fe3O4@GO-MIPs had the best adsorption quantity of 31.9 mg/g. The rebinding experiments indicated that Fe3O4@GO-MIPs not only have outstanding affinity and selectivity towards L-Trp over structurally related compounds but also easily reach the magnetic separation under an external magnetic field.
© The Authors, published by EDP Sciences, 2017
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